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Stereochemistry of ene reactions of glyoxylate esters

✍ Scribed by Snider, Barry B.; Van Straten, Jan W.

Book ID
126440477
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
671 KB
Volume
44
Category
Article
ISSN
0022-3263

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Stereochemistry of the glyoxylate N-sulf
Stereochemistry of the glyoxylate N-sulfonylimine ene reaction
✍ David M. Tschaen; Steven M. Weinreb πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 194 KB

Ene reactions of sulfonylimine J& with cyclohexene and trans-2-butene are highly stereoselective, affording products 2 and l0, respectively. Recently, Achmatowicz reported that N-toluenesulfonylimine & derived from n-butyl glyoxylate undergoes facile ene reactions thermally or under Lewis acid cata