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Ene reactions of dialkyl dioxosuccinate esters

✍ Scribed by Beak, Peter; Song, Zhiguo; Resek, James E.

Book ID
111682099
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
528 KB
Volume
57
Category
Article
ISSN
0022-3263

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## Abstract Photooxygenation of methyl (__E__)‐ and (__Z__)‐2‐methyl‐4‐phenyl‐2‐pentenecarboxylates (__E__‐1, __Z__‐1) afforded the hydroperoxy esters (__R__\*,__S__\*)‐2a and (__S__\*,__S__\*)‐2b through regiospecific and diastereo‐selective ene reaction of singlet oxygen at the α‐methyl group wit