Stereochemistry of Enacyloxins. Part 4. Complete Structural and Configurational Assignment of the Enacyloxin Family, a Series of Antibiotics from Frateuria sp. W-315.

Stereochemistry of Enacyloxins. Part 4 :

Stereochemistry of Enacyloxins. Part 4 : Complete Structural and Configurational Assignment of the Enacyloxin Family, a Series of Antibiotics from Frateuria sp. W-315

✍ Hiroyuki Furukawa; Hiromasa Kiyota; Teiko Yamada; Manabu Yaosaka; Ryo Takeuchi; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB

## Abstract The absolute configurations of the enacyloxins, a series of polyhydroxylated polyene antibiotics from __Frateuria__ species, were determined. The so far elusive (13′__R__,14′__R__,15′__S__)‐configuration was assigned to enacycloxin IVa (**1**) by means of ‘__J__‐resolved HMBC‐1’ and NOE