Stereochemistry of benzenesulphehyl chloride addition to a strained cyclobutene

✍ Scribed by Goverdhan Mehta; Paras N.Pandey

• Publisher: Elsevier Science
• Year: 1975
• Tongue: French
• Weight: 122 KB
• Volume: 16
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)91369-8

✦ Synopsis

Blectrophilic additions of sulphenyl chlorides to olefins have been extensively studied and are considered to be highly stereospecific trans-additions proceeding in two steps via episulphonium (thiiranium) ion intennediates.l Simple olefins like cyclohexene 2a as well as strained olefins e.g.,noroornene, 2b'3 bicy-