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Stereochemistry of Asymmetric Silicon. V. Coupling Reactions with Organometallic Reagents and Displacements of Chloride and Fluoride Leaving Groups

โœ Scribed by Sommer, L. H.; Korte, W. D.; Rodewald, P. G.


Book ID
126286947
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
937 KB
Volume
89
Category
Article
ISSN
0002-7863

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Stereochemistry of asymmetric silicon: C
โœ L.H. Sommer; P.G. Rodewald; G.A. Parker ๐Ÿ“‚ Article ๐Ÿ“… 1962 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 160 KB

ONE of the most useful methods for establishing carbon-silicon bonds is the coupling reaction of organometallic reagents with silicon-halogen and silicon-alkoxy compounds. We wish to report new stereochemical data which bear on the problem of the mechanisms of these interesting reactions. These data