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Stereochemistry of aplidiasphingosine as proposed by the asymmetric synthesis and 13c-nmr study of sphingosine relatives

✍ Scribed by Kenji Mori; Takeaki Urnemura

Book ID: 104235276
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 235 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)82976-2

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✦ Synopsis

The Sharpless asymmetric epoxidation was used for the synthesis of D-erythro-dihydrosphingosine triacetate and (22, dimethyl-8-decene-1,3-diol, 35, 5R)-2-acetamino-5,9whose 13C-NMR study couplea with biogenetic consideration enabled us to propose (22, aplidiasphingosine.

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