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Stereochemistry of addition of disulfonium dications to alkenes

โœ Scribed by N. E. Shevchenko; V. G. Nenajdenko; V. M. Muzalevskii; E. S. Balenkova

Book ID
106519382
Publisher
Springer
Year
2004
Tongue
English
Weight
327 KB
Volume
53
Category
Article
ISSN
1573-9171

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โœ W.Roy Jackson; Craig G. Lovel ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 215 KB

Reactions of both terminal and cyclic alkenes have been shown to occur in a stereospecifically cis -manner with deuterium cyanide when a catalyst system based on -Pd(DIOP), was used. Reactions of cyclohexene give only the products of equatorial cyanide incorporation.