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Stereochemistry of a carbonium ion rearrangement

โœ Scribed by ALLEN, F. H.; KENNARD, OLGA; NASSIMBENI, L. R.; SHEPHERD, R. G.; WARREN, STUART


Book ID
109690078
Publisher
Nature Publishing Group
Year
1974
Tongue
English
Weight
173 KB
Volume
248
Category
Article
ISSN
0028-0836

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Carbonium ion rearrangements controlled
โœ Ian Fleming; Shailesh K Patel ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 232 KB

Tertiary alcohols with a y-silyl group (3) generally undergo a simple carbonium ion rearrangement in acid giving a single alkene product (4) with loss of the silyl group. We reported earlier several examples of carbonium ion rearrangements of the general type (1 + 2) in which the migrating group R