Stereochemistry and Mechanism of the Brønsted Acid Catalyzed Intramolecular Hydrofunctionalization of an Unactivated Cyclic Alkene
✍ Scribed by Rachel E. McKinney Brooner; Prof. Ross A. Widenhoefer
- Book ID
- 118282845
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 385 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The combined use of a copper halide, a silver salt and a phosphane ligand was applied for the catalysis of inter-and intramolecular hydroamination of alkenes. The reactions of unactivated olefins with nitrogen substrates were investigated. Mechanistic investigations demonstrated that the cat-alytic
2-Methyl-1-alkenes have exhibited anomalous reaction behavior over a Re O -Al O metathesis catalyst. Self-metathe- sis of 2-methyl-1-alkenes did not occur at all and several kinds of dimers were formed as major products. The dimer structures using 2-methyl-1-pentene as a model compound were identif