✦ LIBER ✦
Inter- and Intramolecular Hydroamination of Unactivated Alkenes Catalysed by a Combination of Copper and Silver Salts: The Unveiling of a Brønstedt Acid Catalysis
✍ Scribed by Christophe Michon; Florian Medina; Frédéric Capet; Pascal Roussel; Francine Agbossou-Niedercorn
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 390 KB
- Volume
- 352
- Category
- Article
- ISSN
- 1615-4150
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✦ Synopsis
The combined use of a copper halide, a silver salt and a phosphane ligand was applied for the catalysis of inter-and intramolecular hydroamination of alkenes. The reactions of unactivated olefins with nitrogen substrates were investigated. Mechanistic investigations demonstrated that the cat-alytic system generated a Brønsted acid which appeared to be the prominent catalytic species.