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Stereochemistry and mechanism of palladium(II)-induced ring opening of the cyclopropane in a vinylcyclopropane. Chloro- and oxypalladation of (+)-2-carene

โœ Scribed by Wilhelm, Didier.; Baeckvall, Jan E.; Nordberg, Ruth E.; Norin, Torbjorn.


Book ID
126301837
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
869 KB
Volume
4
Category
Article
ISSN
0276-7333

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Kinetics and mechanism of the palladium
โœ Merle A. Battiste; Louis E. Friedrich; Bocco A. Fiato ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 202 KB

An example of an interesting and potentially general method for preparing pi-ally1 palladium chloride complexes from reaction of cyclopropeues with palladium (II) chloride was receutly reported. In the specific case cited2, 1,2,3-triphenylcyclopropene (&) was converted to di-~-chlorobis(n-l-chloro-s