✦ LIBER ✦

Kinetics and mechanism of the palladium (II) promoted ring opening of tri- and tetrasubstituted cyclopropenes

✍ Scribed by Merle A. Battiste; Louis E. Friedrich; Bocco A. Fiato

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 202 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)71773-4

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✦ Synopsis

An example of an interesting and potentially general method for preparing pi-ally1 palladium chloride complexes from reaction of cyclopropeues with palladium (II) chloride was receutly reported. In the specific case cited2, 1,2,3-triphenylcyclopropene (&) was converted to di-~-chlorobis(n-l-chloro-syn,eyn-l,2,3-triphenylally~)pall~l~(II) In 80% isolated yield.

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