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Stereochemistry and mechanism of aikali metal reductions of cycloalkanones

✍ Scribed by Suresh K. Pradhan; Suhas V. Sohani

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
313 KB
Volume
22
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

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Surmary: An opposite stereoselectivity is observed in the r&cticn of 3d-hydroxy-5j%7-oxo-cholaic acid by alkali notals and by sodiun dithicnite, ccntraty to the results reported' with other cyclic or bicyclic ketones. An electrartrznsfer mechanism follmed by coupling of the ketyl radical with SOI is