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Stereochemistry and conformation of 9,10-diisopropyl-9,10-dihydroanthracenes

✍ Scribed by Herman E. Zieger; David J. Schaeffer; Regina M. Padronaggio


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
201 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction of 9-lithio-lo-ethyl-9,lO_dihydroanthracene, J, with methyl iodide or ethyl bromide has been reported to give high yields of cis-9,lO dialkyl-9,10-dihydro--

anthracenes & DHA = dihydroanthracene]. 1'2 Only for reactions of 1 with carbon dioxide


πŸ“œ SIMILAR VOLUMES


Photochemistry of 9,10-Dicarbonyl-9,10-d
✍ Hans Henning Wenk; Wolfram Sander πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 116 KB

9,10-Didehydroanthracene ( 1) is an interesting derivative of which is formed by monodecarbonylation of 2. Carbene 7 is labile towards visible-light irradiation and easily looses the p-benzyne that has been subject of several studies. In contrast to an earlier report, the photochemical second CO mol