Crystalline and molecular structure of 10,10-dichloro-10-germa-9-oxa-9,10-dihydroanthracene
β Scribed by A. I. Udel'nov; V. E. Shklover; N. G. Bokii; E. A. Chernyshev; T. L. Krasnova; E. F. Shchipanova; Yu. T. Struchkov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1974
- Tongue
- English
- Weight
- 419 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0022-4766
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The reaction of 9-lithio-lo-ethyl-9,lO\_dihydroanthracene, J, with methyl iodide or ethyl bromide has been reported to give high yields of cis-9,lO dialkyl-9,10-dihydro-- anthracenes & DHA = dihydroanthracene]. 1'2 Only for reactions of 1 with carbon dioxide
X-ray analysis of the title complex revealed hydrogen-bonded chains comprising two crystallographically independent types of trans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene molecules, in which the central 1,4-cyclohexadiene rings are respectively flat and very slightly puckered, with Che e