Stereochemical studies of epoxide formation from singlet oxygen reactions
β Scribed by Wataru Ando; Yoshio Kabe; Toshikazu Takata; Katsuhiko Ueno
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 405 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0047-2670
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chain reaction already accepted in the case of other bicy-cl~[l.l.O]butanes[~~. Why does the phenylthio radical attack benzvalene (1) at the double bond but homobenzvalene (8) at the bicy-clot1 .I .O]butane system? Since thio radicals have electrophilic characterf7I, the interaction with the HOMO o
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## Photolysis of ozone oxygen mkxtures at 2537 d has been found to produce O,(lc+) and 0 (h 02(lZg) was produced by energy transfer from O(lD) and the 02(lAg) by the prim&y photo ysl ).