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Selective Formation of Allylic Hydroperoxides via Singlet Oxygen Ene Reaction

✍ Scribed by Michael Orfanopoulos; Georgios C. Vougioukalakis; Manolis Stratakis


Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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📜 SIMILAR VOLUMES


Reaction of Singlet Oxygen with 2-Methyl
✍ Charles W. Jefford; André F. Boschung 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 963 KB

## Abstract The dye‐sensitized photo‐oxygenation of 2‐methylnorbonr‐2‐ene (**3**), 2‐methylidene‐norbornane (**4**) and their 7,7‐dimethyl derivatives (**5** and **6**) has been studied. In all cases allylically rearranged hydroperoxides were formed, except that **4** also gave a little norbornanon