Stereochemical studies by mass spectrometry: C15Nuphar alkaloids
✍ Scribed by O. Bortolini; G. Fantin; O. Curcuruto; P. Traldi; A. Iwanow; J. T. Wróbel
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 307 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Representative C,, Nuphar alkaloids, containing the quinolizidine system, were studied by high-resolution mass spectrometry and metastable-ion decomposition analysis. The appearance with N-oxide species of ions at m/z 168, useful in ascertaining the stereochemistry of the quinolizidinic ring junction, are ako discussed.
📜 SIMILAR VOLUMES
## Abstract The configurations of anagyrine, thermopsine and two other anagyrine‐type quinolizidine alkaloids were revised using ^15^N and 2D NMR in a 400 MHz NMR study. Their ^1^H and ^13^C NMR chemical shifts are given in detail.