Stereochemical factors in the intramolecular keto-carbene addition to substituted cyclohexenes
β Scribed by Patrick M. McCurry Jr.
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 185 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The unusual stability of phenylsulfinyl carbene, signalled by (1) the ease by which it is formed unimolecularly from phenyl diazomethyl sulfoxide, (2) the lack of C-H insertion reactions, and (3) the high degree of stereoselectivity in cycloaddition to Z-2-butene and cyclohexene, 2 strongly suggests
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