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A comprehensive approach to the stereochemical and physical factors in nucleophilic substitution on PVC in the melt

✍ Scribed by C. Mijangos; J. M. Gómez-Elvira; G. Martínez; J. Millán


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
677 KB
Volume
38
Category
Article
ISSN
0021-8995

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Stereoselective nucleophilic substitutio
✍ C. Mijangos; G. Martínez; A. Méndez; J.M. Gómez-Elvira; J. Millán 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 289 KB

The nucleophilic substitution of a commercial poly(vinyl chloride) sample, with sodium benzenethiolate, was studied at 150 ° in dioctylphthalate (DOP), in which the polymer and the nucleophile are soluble and insoluble, respectively. Some experiments of substitution in the melt in the presence of mo