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Stereochemical evidence for pseudorotation in the reaction of a phosphoric monoester

โœ Scribed by Buchwald, Stephen L.; Pliura, Diana H.; Knowles, Jeremy R.

Book ID
120002043
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
958 KB
Volume
106
Category
Article
ISSN
0002-7863

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work (1) haa Indicated that there is a substantial elmllarlty between the mechanism of the thermal decomposition of aralkyl thiocarbonates (ep. 1) and the me&a&m of the decomposition of chlorocarbonates (cq. 2). The latter reaction is usually cited as a typical