✦ LIBER ✦

Stereochemical effects in mass spectrometry: Part 8-chemical ionization mass spectra of cyclic glycols and monosaccharides using formaldehyde dimethyl acetal as reagent gas

✍ Scribed by Ya-Ping Tu; Yao-Zu Chen; Su-Nian Chen; Mei-Lan Wang; Zhi-Zhong Jing

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 282 KB
Volume: 25
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210250104

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✦ Synopsis

Abstract

The chemical ionization mass spectra of cyclic glycols and monosaccharides using formaldehyde dimethyl acetal as reagent gas have been studied. In the gas phase, the stereospecific reaction of methylene acetal formation was observed. From the relative abundances of the characteristic ions the stereoisomers of these compounds may be definitely distinguished.

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