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Stereochemical effects in mass spectrometry. Part 10-reaction mass spectrometry of cyclic glycols and monosaccharides with methylene chloride as reagent gas

✍ Scribed by Ya-Ping Tu; Guan-Yu Yang; Yu-Hua Liu; Shao-Nong Chen; Yao-Zu Chen

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
289 KB
Volume
26
Category
Article
ISSN
1076-5174

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✦ Synopsis

The reaction mass spectrometry of cyclic glycols and monosaccharides with methylene chloride as reagent was studied. In the presence of ammonia, it was found that methylene chloride reacted stereoselectively with the quasimolecular ions of cyclic glycols and monosaccharides to form characteristic ions, by comparison of the relative abundances of which the stereoisomers of cyclopentane-l,%diols and cyclohexane-1,2-diols and some monosaccharides could be definitely distinguished.

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