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Stereochemical Control in the Anionic Polymerization of β-Butyrolactone Initiated with Alkali-Metal Alkoxides

✍ Scribed by Jedliński, Zbigniew; Kowalczuk, Marek; Kurcok, Piotr; Adamus, Grażyna; Matuszowicz, Andrzej; Sikorska, Wanda; Gross, Richard A.; Xu, Jin; Lenz, Robert W.


Book ID
120452224
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
167 KB
Volume
29
Category
Article
ISSN
0024-9297

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Substituent effect in anionic polymeriza
✍ Piotr Kurcok; Andrzej Matuszowicz; Zbigniew Jedliński; Hans R. Kricheldorf; Phil 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB

## Abstract The influence of methyl substituent on the mechanism of the ring‐opening polymerization of β‐lactones initiated by alkali metal alkoxides is discussed. Attention has been paid to the effect of the substituent position in the monomer molecule on the ring‐opening mechanism, the 3,3‐dimeth