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Anionic polymerization of .beta.-lactones initiated with alkali-metal alkoxides: reinvestigation of the polymerization mechanism

โœ Scribed by Kurcok, Piotr; Kowalczuk, Marek; Hennek, Krystian; Jedlinski, Zbigniew


Book ID
120445696
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
440 KB
Volume
25
Category
Article
ISSN
0024-9297

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Substituent effect in anionic polymeriza
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## Abstract The influence of methyl substituent on the mechanism of the ringโ€opening polymerization of ฮฒโ€lactones initiated by alkali metal alkoxides is discussed. Attention has been paid to the effect of the substituent position in the monomer molecule on the ringโ€opening mechanism, the 3,3โ€dimeth