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Stereochemical assignment of (E)- and (Z)-2-(1-naphthyl)-1-phenylpropene and their photocyclization to 5-methylchrysene

✍ Scribed by Browne, Clinton E.; Dobbs, Thomas K.; Hecht, Stephen S.; Eisenbraun, Edmund J.

Book ID: 127057751
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 683 KB
Volume: 43
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00403a007

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## Abstract The configuration and conformation of __Z__‐ and __E__‐__N__‐methyl‐ and ‐__N__‐benzyl‐2‐__p__‐nitrophenyl‐4,5‐, and ‐5,6‐tetramethylenetetrahydro‐1,3‐oxazines were determined by ^1^H and ^13^C NMR spectroscopy. The __Z__ isomers were proved to be conformationally homogeneous, having th