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A highly efficient synthesis of (Z)-1-aryl-2-silyl-1- stannylethenes and their conversion to (E)-2- arylethenyl-, (Z)-2-(2-pyridyl)ethenyl- and allenyl-silanes

✍ Scribed by Takanori Endo; Fumio Sasaki; Hisashi Hara; Jyunko Suzuki; Shizuka Tamura; Yoshikazu Nagata; Tetsuro Iyoshi; Atsuhiro Saigusa; Taichi Nakano

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
268 KB
Volume
21
Category
Article
ISSN
0268-2605

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## Abstract Stereospecific synthesis of a family of novel (__E__)‐2‐aryl‐1‐silylalka‐1,4‐dienes or (__E__)‐4‐aryl‐5‐silylpenta‐1,2,4‐trienes via a cross‐coupling of (__Z__)‐silyl(stannyl)ethenes with allyl halides or propargyl bromide is described. In the reaction with allyl bromide, either a Pd(db