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Stereochemical aspects of the Claisen rearrangement of allyl vinyl ethers

โœ Scribed by House, Herbert O.; Lubinkowski, Jacek; Good, James J.


Book ID
126172258
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
966 KB
Volume
40
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES


Palladium(II)-catalyzed claisen rearrang
โœ J.L van der Baan; F Bickelhaupt ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl