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Organoaluminum-promoted Claisen rearrangement of allyl vinyl ethers

โœ Scribed by Nonoshita, Katsumasa; Banno, Hiroshi; Maruoka, Keiji; Yamamoto, Hisashi


Book ID
120647782
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
1012 KB
Volume
112
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Organoaluminum-promoted Claisen rearrang
โœ Keiji Maruoka; Hiroshi Banno; Katsumasa Nonoshita; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 129 KB

## The Claisen rearrangement of bisally1 vinyl ethers with exceptionally bulky organoaluminum reagents exhibits unprecedented regiochemical control not observable in the ordinary thezvtal rearrangement.

Organoaluminum-promoted rearrangement of
โœ Keiji Maruoka; Junko Sato; Hiroshi Banno; Hisashi Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

## The Claisen rearrangement of ally1 phenyl ethers with exceptionally bulky, oxygenophilic methylaluminum bis(4-bronro-2,6-di-terr-buty$henoxide) (reagent A) is found to exhibit an unusual behavior twt observable in the ordinary thermal and LAMS acid-induced rearrangement. The Claisen rearrangem

Palladium(II)-catalyzed claisen rearrang
โœ J.L van der Baan; F Bickelhaupt ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

The Claisen rearrangement of ally1 vinyl ethers is catalyzed by PdCQ(CH3CN)Z. provided that alkyl substituents protect the vinyl ether double bond from coordination by the metal catalyst. [3,3]Sigmatropic rearrangements are very useful for the formation of C-C, C-O, C-N and C-S bonds. Besides the cl