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Stereochemical aspects of the biological oxidation of aryl isoprenoids. The asymmetric synthesis and absolute configuration of meranzin and of meranzin hydrate

โœ Scribed by Michael F. Grundon; Ian S. McColl

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
651 KB
Volume
14
Category
Article
ISSN
0031-9422

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The first asymmetric synthesis of the na
The first asymmetric synthesis of the naturally occurring (+)-Kotanin and the assignment of its absolute configuration
โœ Guo-Qiang Lin; Min Zhong ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 241 KB

The first asymmetric synthesis of the naturally occurring (+)-Kotanin is described. The key steps involve the intramolecular oxidative coupling of the cyanocuprate intermediate and the Fries rearrangement. The absolute configuration of (+)-Kotanin was assigned as aS by CD spectroscopic method. (~) 1