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Stereo-selective synthesis of Erythro-3-methyl-hexyn-3,4-diol

✍ Scribed by Christiane Santelli-Rouvier; Maurice Santelli

Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
187 KB
Volume
23
Category
Article
ISSN
0040-4039

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v5+ -Catalyzed t-butylhydroperoxide epoxidation of (Z)-5-hydroxy-2- alkenylsilanes 4 exhibit good to excellent ervthro selectivity. The resulting epoxides undergo fragmentation to afford 1,3-diols 8, albeit in low chemical yield. Many natural products of current interest contain either a 1,3-diol s