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Stereo- and Regioselective Synthesis of Enantiomerically Pure (+)- and (−)-Hexahydrocannabinol by Intramolecular Cycloaddition

✍ Scribed by Prof. Dr. Lutz-F. Tietze; Günter von Kiedrowski; Bernhard Berger


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
205 KB
Volume
21
Category
Article
ISSN
0044-8249

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Syntheses of (±)- and Enantiomerically P
✍ Wolfgang Oppolzer; Thierry Godel 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 973 KB

## Abstract Starting from 2‐cyclopentenoyl chloride ((__RS__)‐ or (__S__)‐**8**), the racemic as well as the enantiomerically pure (+)‐sesquiterpenes longifolene ((±)‐ and (+)‐**1**, resp.) and sativene ((±)‐ and (+)‐**2**, resp.) were synthesized efficiently by a sequence of nine and ten steps, re