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Stepwise synthesis and properties of a 9,10-dihydro-9,10-diboraanthracene

✍ Scribed by Tomohiro Agou; Masaki Sekine; Takayuki Kawashima

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 368 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.07.068

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✦ Synopsis

A stepwise synthetic method for a 9,10-dihydro-9,10-diboraanthracene was developed, and the optical and electrochemical properties as well as the molecular structure of the 9,10-dihydro-9,10-diboraanthracene were elucidated. The 9,10-dihydro-9,10-diboraanthracene exhibited high complexation ability against fluoride ion, and the complexation was accompanied by the enhancement of photoluminescence emission, probably due to intramolecular charge transfer between the two boron atoms.

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