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9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers

✍ Scribed by Andreas Lorbach; Michael Bolte; Haiyan Li; Hans-Wolfram Lerner; Max C. Holthausen; Frieder Jäkle; Matthias Wagner

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
560 KB
Volume
48
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Building bridges: The title compound forms an unprecedented polymeric structure with bridging B–H–B three‐center two‐electron bonds in the solid state. This organoborane serves as an efficient precursor for the preparation of boron‐doped π‐conjugated polymers by hydroboration polymerization with a functionalized 1,4‐diethynylbenzene (see picture). These polymers form thin films that show intense green luminescence.magnified image

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9,10-Dihydro-9,10-diboraanthracene: Supr
9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers
✍ Andreas Lorbach; Michael Bolte; Haiyan Li; Hans-Wolfram Lerner; Max C. Holthause 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 560 KB

## Abstract **Dreizentren‐Zweielektronen‐B‐H‐B‐Brücken** kennzeichnen die neuartige polymere Struktur der Titelverbindung im Festkörper. Dieses Organoboran dient als effiziente Vorstufe für die Herstellung bordotierter π‐konjugierter Polymere durch Hydroborierungspolymerisation mit einem funktional