Step-Growth “Click” Coupling of Telechelic Polymers Prepared by Atom Transfer Radical Polymerization
✍ Scribed by Tsarevsky, Nicolay V.; Sumerlin, Brent S.; Matyjaszewski, Krzysztof
- Book ID
- 115480221
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 96 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Initiators for atom transfer radical polymerization (ATRP) bearing different functional groups (aldehyde, aromatic hydroxyl, dimethyl amino) were synthesized and characterized. Monotelechelics with low molecular weight were obtained by ATRP of styrene using these initiators in the prese
Hydrolysis of 4-acetoxystyrene polymers prepared by atom transfer radical polymerization was carried out under various reaction conditions. It was found that hydrazinolysis of 4-acetoxystyrene homopolymers, random and block copolymers with styrene in 1,4-dioxane, afforded the corresponding narrow di