Preparation of hyperbranched polymers by atom transfer radical polymerization
β Scribed by Jiang Bibiao; Yang Yang; Deng Jian; Fu Shiyang; Zhu Rongqi; Hao Jianjun; Wang Wenyun
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 142 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0021-8995
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Hydrolysis of 4-acetoxystyrene polymers prepared by atom transfer radical polymerization was carried out under various reaction conditions. It was found that hydrazinolysis of 4-acetoxystyrene homopolymers, random and block copolymers with styrene in 1,4-dioxane, afforded the corresponding narrow di
Polymers prepared by atom transfer radical polymerization (ATRP) contain end groups defined by the initiator used. Alkyl halides, used as initiators, lead to polymers with an alkyl group at one end and a halide as the other chain end. Using functionalized initiators such as 2-hydroxyethyl 2-bromopro