Steam and heat setting of nylon 6 fiber. VI. Water adsorption on nylon 6 fiber
β Scribed by A. Koshimo; T. Tagawa
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- English
- Weight
- 450 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Water adsorption of nylon 6 fibers subjected to various heat-aetting treatments waa measured over the range of &SO% R.H. with a quartz balance, and the water adsorbed on the 6rat layer (urn) waa calculated. The value of urn waa largest for uneet fibr, intermediate for steam-eet fiber, and the smallest for dry-heahet fiber. The inner surface are^ in nylon calculated from v,,, are 4-5 X 1W cm.*/g. The value obtained by dividing vm by the amorphoua fraction (1a) of heat-& fibers appeam to be related to the number of intermolecular bond per unit volume of the amorphous region. The smaller values of urn thus obtained for the dry-heat-aet fibem indicate that polymer molecules in the amorphoua region form many intermolecular bonds and are more closely packed than those in the unaet and steam-& fibers.
π SIMILAR VOLUMES
## SJnopSis The swelling and dissolution of heat-& nylon 6 fiber in aqueoum eulfuric acid were examined. Stesm-set fiber having good dyeability swelle with much more difficulty than the dry-heat-aet and umet fibers. Similar phenomena are seen in the examination of dedty of .nylon 6 fiber eubjected
The present work compared the recrystallization process of Nylon 6 with Nylon 6.6 fibers. For such a study, the fibers were submitted to different annealing conditions (slack and restrained conditions) in a wide range of temperatures. For the structural analysis, several techniques were applied, and