Diffusion coefficients for water in high permeability ionomers are determined from steady state permeation measurements, corrected for boundary layer resistance and change in vapor concentration along sample length, to circumvent problems due to heat of condensation and structural relaxation. Values
Steady-state rate analysis: application to biological transport
β Scribed by Jonathan Wagg; Brian J. Chapman
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 577 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0022-5193
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β¦ Synopsis
A novel method for defining the steady-state unidirectional rates of complex reactions has previously been developed (Wagg, 1988 Ph.D. Thesis, Monash University, Australia). This methodology is based upon the method of Wagg (1987, J. theor. Biol. 128, 375-385) for defining the steady-state unidirectional fluxes of chemical species through branched chemical, osmotic and chemiosmotic reactions. It offers a number of distinct advantages over existing approaches to steady-state rate analysis: it is relatively simple to apply to complex reactions and is readily amenable to computer-based application. The method is demonstrated by direct application to a number of hypothetical models for biological transport phenomena.
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## Abstract In this work, we present the postβsteady state analysis of the TCA cycle and a closed form solution to the rate of label washout from the C4 carbon of glutamic acid through the transaminases and the malateβaspartate shuttle and then through Ξ±βketoglutarate dehydrogenase. We demonstrate