Steady-state kinetics of the NO-CO reaction on Rh(111): extrapolation from 10−10to 1 bar

Determination of the activation barrier

Determination of the activation barrier to energy transfer from 3ππ* to charge transfer levels via steady-state and transient luminescence measurements on bis(4-chlorothiophenol)(1,10-phenanthroline)zinc(II)

✍ R.G. Highland; G.A. Crosby 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The effect of rcmpcr~mre on the lummescence m~cns~~ and excrrcd stale lircllmrs of rhc r~dc compound is inwrpreled in terms or a barrier LO the IKUISTIX or energy rrom the IOUT\_Q %e lerel IO loner-lying charge-transfer Icvcl~ FIIS or an Arrhenius expression LO borh Ilrclimes and relawe tnrenslttcs