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Statistical theories of main chain scission and crosslinking of polymers—application to the photolysis and radiolysis of polystyrene studied by gel permeation chromatography

✍ Scribed by C. David; D. Baeyens-Volant

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
711 KB
Volume
14
Category
Article
ISSN
0014-3057

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✦ Synopsis

The statistical theories of main chain scission and crosslinking resulting from either homogeneous or inhomogeneous energy dissipation in polymers are summarized. The molecular weight distributions of polystyrene samples subjected in vacuo to 7-rays (homogeneous energy dissipation) or to U.V. irradiation (inhomogeneous energy dissipation) have been measured by GPC for various absorbed doses. The results are discussed according to these theories.

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