Coupling of gel permeation chromatography and automatic viscometry. application to the study of long chain branched polyethylene
β Scribed by D. Constantin
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 494 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0014-3057
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β¦ Synopsis
An automatic viscometer coupled with a GPC instrument is reported. The calculations which are briefly described give the molecular weight distribution corrected for long-chain branching effect, the variations of the structure parameter 9' and of the long-chain branching frequency 2 with molecular weight. We state the assumptions, among them the Zimm-Kilb formula for the conversion of hydrodynamic dimensions to geometric dimensions (O' = gx) with 0.5 as an exponent and a Zimm-Stockmayer formula giving in a second step 2 from g in the case of tetrafunctional branch points. The results on two samples of LDPE are presented in detail. The long-chain branching frequency increases with molecular weight in the region of high molecular weight. Other assumptions have been tested on the same LDPE samples with different values of x (1, 1.5, increasing with M.W.), tri-or tetrafunctionat branch points. These assumptions appear to give no differentiation between the products (no more variation of 2 with M.W.) and some theoretical reasons to exclude them are given. Another application of viscometer-GPC coupling is the direct determination of solution viscosity relations for linear polymers (HDPE, PB-I) without using absolutely characterized standards. Some observations about axial dispersion are given.
π SIMILAR VOLUMES
A comparison is made of two methods by which one may derive molecular weight distribution and degree of long-chain branching using only the measured solution viscosity of a branched polyethylene whole polymer and its GPC trace. These are (a) Drott and Mendelson method and (b) Ram and Miltz procedure
The statistical theories of main chain scission and crosslinking resulting from either homogeneous or inhomogeneous energy dissipation in polymers are summarized. The molecular weight distributions of polystyrene samples subjected in vacuo to 7-rays (homogeneous energy dissipation) or to U.V. irradi