✦ LIBER ✦

Statistical study of the effect of variation of bimolecular rate constant in condensation polymerization

✍ Scribed by Nanda, V. S. ;Jain, S. C.

Publisher: Wiley (John Wiley & Sons)
Year: 1970
Tongue: English
Weight: 497 KB
Volume: 8
Category: Article
ISSN: 0449-296X
DOI: 10.1002/pol.1970.150080723

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✦ Synopsis

Abstract

We investigate the effect of variation of bimolecular rate constant with chain length on condensation polymerization by a statistical approach. The variation of reactivity with chain length is simulated in the present study by assigning appropriate weight factors to different species. Formal expressions for the size distribution and various averages of interest have been obtained. Some simple cases are then analyzed and comparisons with the experimental results of Taylor and Howard are carried out.

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