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Statistical phase space theory of polyatomic systems. Application to the cross section and product kinetic energy distribution of the reaction C2H4.cntdot.+ + C2H4 .fwdarw. C3H5+ + CH3

✍ Scribed by Chesnavich, W. J.; Bowers, M. T.


Book ID
126042255
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
959 KB
Volume
98
Category
Article
ISSN
0002-7863

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Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+

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Kinetics of the reactions H t C2H4+C2H5, H+C2Hs-+2CH3 and CH3 t C2HS-+ products studied by pulse radiolysis combined with infrared diode laser spectroscopy (Chem. Phys. Letters 20 1 ( 1993 ) 17 1)