Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+
✦ LIBER ✦
Kinetics of the reactions H+C2H4→C2H5, H+C2H5→2CH3 and CH3+C2H5→ products studied by pulse radiolysis combined with infrared diode laser spectroscopy (Chem. Phys. Letters 201 (1993) 171)
✍ Scribed by A. Sillesen; E. Ratajczak; P. Pagsberg
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 31 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Kinetics of the reactions H t C2H4+C2H5, H+C2Hs-+2CH3 and CH3 t C2HS-+ products studied by pulse radiolysis combined with infrared diode laser spectroscopy (Chem. Phys. Letters 20 1 ( 1993 ) 17 1)
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