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Statistical Copolymers of l,l-lactide and ε-caprolactone

✍ Scribed by MariaLeonora Castro; ShuHui Wang

Publisher
Springer
Year
2003
Tongue
English
Weight
491 KB
Volume
51
Category
Article
ISSN
0170-0839

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## Abstract Biodegradable and photocurable block copolymers of __ε__‐caprolactone and L‐lactide were synthesized by polycondensation of PLLA diol ($\overline {M} \_{{\rm n}} $ = 10 000 g · mol^−1^), PCL diol ($\overline {M} \_{{\rm n}} $ = 10 000 g · mol^−1^), and a chain extender bearing a coumari

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## Abstract L,L‐lactide (LA) and __ε__‐caprolactone (CL) block copolymers have been prepared by initiating the poly(__ε__‐caprolactone) (PCL) block growth with living poly(L,L‐lactide) (PLA\*). In the previous attempts to prepare block copolymers this way only random copolyesters were obtained beca

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## Abstract Cross‐linked __ε__‐caprolactone (CL) and D,L‐lactide (DLLA) copolymers with elastic properties were synthesized in three steps. First, the monomers were copolymerized in ring‐opening polymerization to obtain telechelic star‐shaped oligomers with almost completely random monomer distribu

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## Abstract For the triblock copolymer of ε‐caprolactone, trimethylene carbonate, and L‐lactide, where L‐lactide blocks form the two ends, there is a range of compositions over which elastomeric behavior is obtained. Within this composition range, these polymers show good creep and recovery at ambi