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Segmental dynamics in poly(ε-caprolactone)/poly(L-lactide) copolymer networks

✍ Scribed by Roser Sabater i Serra; Jorge L. Escobar Ivirico; Jose María Meseguer Dueñas; Andreu Andrio Balado; José Luis Gómez Ribelles; Manuel Salmerón Sánchez

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
540 KB
Volume
47
Category
Article
ISSN
0887-6266

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## SYNOPSIS Blends of poly(L-lactide) (PLLA) and poly(e-caprolactone) (PCL) were prepared in a corotating twin screw miniextruder (40 rpm, 200"). It was attempted to prepare multiblock copolymers by allowing a controlled number of transesterification reactions. Various catalysts (n-Bu,SnOMe, Sn(Oc

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## Abstract **Summary:** Poly(L‐lactide) (PLLA) and poly(__ε__‐caprolactone) (PCL) ultrafine fibers were prepared by electrospinning. The influence of cationic and anionic surfactants on their enzymatic degradation behavior was investigated by measuring weight loss, molecular weight, crystallinity,