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Static and dynamic effects in the EPR spectra of [A(H2O)6]BF6systems

✍ Scribed by R. Hrabański; A. Kassiba

Book ID
105719392
Publisher
Springer Vienna
Year
1997
Tongue
English
Weight
491 KB
Volume
12
Category
Article
ISSN
0937-9347

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✍ L. Asch; I. Dézsi; T. Lohner; B. Molnár 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 205 KB

The Miissbauer spectra of iron and cobalt fluoroborate hexahydrate show a change by a factor of two in the quadrupole interaction near 2%) K and 185 K, respectively, togtther with a sudden drop in resonance fraction. This behaviour is explained as a first order phase transition in which the axial pa