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State-specific orbital alignment effects in electronic energy transfer: Sr(5s6p 1P1)+M→Sr(5s6p 3Pj, 4d5p 3F4, 3F3)+M

✍ Scribed by Wolfgang Bussert; Stephen R. Leone

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 568 KB
Volume: 138
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80380-9

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✦ Synopsis

Orbital alignment effects are investigated for an energy transfer process involving several competing pathways in the system Sr( 5s6p 'P, ) + rare gases and Hz. Most of the cross sections to populate either (I ) the combined 5s6p 'P, and 4d5p 3Fq states or

(2) the individual 4d5p 3Fg level show a marked preference for the perpendicular approach of the p orbital. However the cross section with He to populate the 'F3 state strongly favors the parallel orbital direction.

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