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Orbital alignment effects in the Ca(4s5p1P1)to Ca(4s5p3Pj) electronic energy transfer with molecular collision partners

โœ Scribed by Wolfgang Bussert; Stephen R. Leone

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
621 KB
Volume
138
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The effects of orbital alignment on the Ca(4s5p 'P,) to Ca(4sSp'P,) electronic energy transfer process are determined for molecular collision partners, HI, D2, N2, 02, CO, C02, CH,, C2H,, and SF+ Most of the molecules exhibit negligible effects, except for H2 ( D2) and CO*, which show significant preferences for perpendicular and parallel initial orbital alignments, respectively. In the reverse transfer direction, hydrogen exhibits an even larger effect favoring the perpendicular laser polarization.

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