Time-resolved studies of the reactions o
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J.E. Baggott; M.A. Blitz; H.M. Frey; P.D. Lightfoot; R. Walsh
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Article
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1987
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Elsevier Science
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English
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We report rate constants for the reactions of SiMez with SiH,,, MeSiH,, Me2SiH2, Me,SiH, Me,Si and pentamethyldisilane obtained using laser flash photolysis/laser absorption techniques. ArF exciplex laser (193 nm) photolysis of pentamethyldisilane was used to generate SiMe2 radicals in the gas phase